A photograph or photo is an image created by light falling on a light-sensitive surface, usually photographic film or an electronic medium such as a CCD or a CMOS chip. Most photographs are created using a camera, which uses a lens to focus the scene's visible wavelengths of light into a reproduction of what the human eye would see. The process and practice of creating photographs is called photography. The word "photograph" was coined in 1839 by Sir John Herschel and is based on the Greek meaning "light", and meaning "drawing, writing", together meaning "drawing with light".After Niépce's death in 1833, Daguerre concentrated on silver halide-based alternatives. He exposed a silver-plated copper sheet to iodine vapor, creating a layer of light-sensitive silver iodide; exposed it in the camera for a few minutes; developed the resulting invisible latent image to visibility with mercury fumes; then bathed the plate in a hot salt solution to remove the remaining silver iodide, making the results light-fast. He named this first practical process for making photographs with a camera the daguerreotype, after himself. Its existence was announced to the world on 7 January 1839 but working details were not made public until 19 August. Other inventors soon made improvements which reduced the required exposure time from a few minutes to a few seconds, making portrait photography truly practical and widely popular.
The daguerreotype had shortcomings, notably the fragility of the mirror-like image surface and the particular viewing conditions required to see the image properly. Each was a unique opaque positive that could only be duplicated by copying it with a camera. Inventors set about working out improved processes that would be more practical. By the end of the 1850s the daguerreotype had been replaced by the less expensive and more easily viewed ambrotype and tintype, which made use of the recently introduced collodion process. Glass plate collodion negatives used to make prints on albumen paper soon became the preferred photographic method and held that position for many years, even after the introduction of the more convenient gelatin process in 1871. Refinements of the gelatin process have remained the primary black-and-white photographic process to this day, differing primarily in the sensitivity of the emulsion and the support material used, which was originally glass, then a variety of flexible plastic films, along with various types of paper for the final prints.
The most stable of plastics used in photo preservation, polyester, does not generate any harmful chemical elements, but nor does it have any capability to absorb acids generated by the photograph itself. Polyester sleeves and encapsulation have been praised for their ability to protect the photograph from humidity and environmental pollution, slowing the reaction between the item and the atmosphere. This is true, however the polyester just as frequently traps these elements next to the material it is intended to protect. This is especially risky in a storage environment that experiences drastic fluctuations in humidity or temperature, leading to ferrotyping, or sticking of the photograph to the plastic.[4] Photographs sleeved or encapsulated in polyester cannot be stored vertically in boxes because they will slide down next to each other within the box, bending and folding, nor can the archivist write directly onto the polyester to identify the photograph. Therefore, it is necessary to either stack polyester protected photographs horizontally within a box, or bind them in a three ring binder. Stacking the photos horizontally within a flat box will greatly reduce ease of access, and binders leave three sides of the photo exposed to the effects of light[7] and do not support the photograph evenly on both sides, leading to slumping and bending within the binder. The plastic used for enclosures has been manufactured to be as frictionless as possible to prevent scratching photos during insertion to the sleeves. Unfortunately, the slippery nature of the enclosure generates a build-up of static electricity, which attracts dust and lint particles. The static can attract the dust to the inside of the sleeve, as well, where it can scratch the photograph.[4] Likewise, these components that aid in insertion of the photo, referred to as slip agents, can break down and transfer from the plastic to the photograph, where they deposit as an oily film, attracting further lint and dust. At this time, there is no test to evaluate the long-term effects of these components on photographs. In addition, the plastic sleeves can develop kinks or creases in the surface, which will scratch away at the emulsion during handling.
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